When I add a new user with a different email address, I get the error message: That username is currently reserved but may be available in a couple of days.

For me, I removed the row from the database in the table wp_signups where user_login equaled the username. Essentially:

delete from wp_signups where user_login = 'abc';

Then I was able to re-add the user.

https://wordpress.stackexchange.com/questions/212671/how-to-work-around-that-email-address-has-already-been-used-error